#
# File created on 2024-04-19 14:00:59 EDT
#
# U.S. Geological Survey
# 
# This file contains selected water-quality data for stations in the National Water 
# Information System water-quality database.  Explanation of codes found in this file are 
# followed by the retrieved data. 
#
# The data you have secured from the USGS NWISWeb database may include data that have 
# not received Director's approval and as such are provisional and subject to revision. 
# The data are released on the condition that neither the USGS nor the United States 
# Government may be held liable for any damages resulting from its authorized or 
# unauthorized use.
#
# To view additional data-quality attributes, output the results using these options:  
# one result per row, expanded attributes.  Additional precautions are at:
# https://help.waterdata.usgs.gov/tutorials/water-quality-data/help-using-the-water-quality-data-retrieval-system#Data_retrievals_precautions
#
#  agency_cd                  - Agency Code
#  site_no                    - USGS site number
#  sample_dt                  - Begin date
#  sample_tm                  - Begin time
#  sample_end_dt              - End date
#  sample_end_tm              - End time
#  sample_start_time_datum_cd - Time datum
#  tm_datum_rlbty_cd          - Time datum reliability code
#  coll_ent_cd                - Agency Collecting Sample Code
#  medium_cd                  - Sample Medium Code
#  tu_id                      - Taxonomic unit code
#  body_part_id               - Body part code
#  parm_cd                    - Parameter code
#  remark_cd                  - Remark code
#  result_va                  - Parameter value
#  val_qual_tx                - Result value qualifier code
#  meth_cd                    - Method code
#  dqi_cd                     - Data-quality indicator code
#  rpt_lev_va                 - Reporting level
#  rpt_lev_cd                 - Reporting level type
#  lab_std_va                 - Lab standard deviation
#  anl_ent_cd                 - Analyzing entity code
#
# The following parameters are included:
#  01005  - Barium, water, filtered, micrograms per liter
#  01010  - Beryllium, water, filtered, micrograms per liter
#  01025  - Cadmium, water, filtered, micrograms per liter
#  01030  - Chromium, water, filtered, micrograms per liter
#  01035  - Cobalt, water, filtered, micrograms per liter
#  01040  - Copper, water, filtered, micrograms per liter
#  01046  - Iron, water, filtered, micrograms per liter
#  01049  - Lead, water, filtered, micrograms per liter
#  01056  - Manganese, water, filtered, micrograms per liter
#  01057  - Thallium, water, filtered, micrograms per liter
#  01060  - Molybdenum, water, filtered, micrograms per liter
#  01065  - Nickel, water, filtered, micrograms per liter
#  01075  - Silver, water, filtered, micrograms per liter
#  01080  - Strontium, water, filtered, micrograms per liter
#  01085  - Vanadium, water, filtered, micrograms per liter
#  01090  - Zinc, water, filtered, micrograms per liter
#  01106  - Aluminum, water, filtered, micrograms per liter
#  01130  - Lithium, water, filtered, micrograms per liter
#
# Description of sample_start_time_datum_cd:
# EDT  - Eastern Daylight Time
#
# Description of tm_datum_rlbty_cd:
# K  - Known
# T  - Transferred
#
# Description of coll_ent_cd and anl_ent_cd:
# USGS-WRD  - U.S. Geological Survey-Water Resources Discipline
# USGSNWQL  - USGS-National Water Quality Lab, Denver, CO
#
# Description of medium_cd:
# WG  - Groundwater
#
# Description of tu_id:
# https://www.itis.gov/
#
# Description of body_part_id:
#
# Description of remark_cd:
# <  - Less than
#
# Description of val_qual_tx:
# n  - below the reporting level but at or above the detection level
#
# Description of meth_cd:
# GF075  - Chromium, wf, GFAAS
# PLA11  - Metals, wf, ICP-AES (NWQL)
# PLM10  - Elements, wf, cICP-MS
# PLM40  - Metals, water, ICP-MS (NWQL)
# PLM43  - Metals, wf, ICP-MS
#
# Description of dqi_cd:
# A  - Historical data
# R  - Reviewed and approved
#
# Description of rpt_lev_cd:
# LRL  - Laboratory reporting level
# LT-MDL  - Long term method detection level
# MRL  - Minimum reporting level
#
# Data for the following sites are included:
#  USGS 353219077153801 PI-532 NC-160 NR SIMPSON, NC SURFICIAL
#
agency_cd	site_no	sample_dt	sample_tm	sample_end_dt	sample_end_tm	sample_start_time_datum_cd	tm_datum_rlbty_cd	coll_ent_cd	medium_cd	tu_id	body_part_id	parm_cd	remark_cd	result_va	val_qual_tx	meth_cd	dqi_cd	rpt_lev_va	rpt_lev_cd	lab_std_va	anl_ent_cd
5s	15s	10d	5d	10d	5d	3s	1s	8s	3s	11s	11s	5s	1s	12s	5s	5s	1s	12s	6s	11s	8s
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01005		91.0		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01010	<	1.00		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01025	<	1.00		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01030		3		PLM40	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01035		3.00		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01040		35.0		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01046		120		PLA11	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01049		479		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01056		20.0		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01060	<	1.00		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01065		5.00		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01075	<	1.00		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01090		47.0		PLM43	A				
USGS	353219077153801	1994-09-07	09:30			EDT	T	USGS-WRD	WG			01106		712		PLM43	A				
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01005		52.2		PLM43	R	1	MRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01010		0.141		PLM43	R	0.06	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01025		0.130		PLM43	R	0.037	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01030	<	0.8		GF075	R	0.8	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01035		3.04		PLM43	R	0.015	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01040		17.4		PLM43	R	0.23	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01046		22.7		PLA11	R	10	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01049		342		PLM43	R	0.16	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01056		16.8		PLM43	R	0.1	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01057		0.225		PLM40	R	0.041	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01060	<	0.200		PLM43	R	0.2	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01065		3.81		PLM43	R	0.06	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01075	<	1.00		PLM43	R	1	MRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01080		18.4		PLM40	R	0.08	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01085		0.5		PLM40	R	0.21	LRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01090		23.3		PLM43	R	1	MRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01106		635		PLM43	R	1	MRL		
USGS	353219077153801	2002-05-09	11:15			EDT	T	USGS-WRD	WG			01130		0.92		PLM40	R	0.3	LRL		
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01005		83.2		PLM43	R	0.25	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01010		0.131		PLM43	R	0.02	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01025		0.163		PLM43	R	0.03	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01030	<	0.30		PLM10	R	0.3	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01035		4.58		PLM10	R	0.05	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01040		2.6		PLM10	R	0.8	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01046		12.2		PLA11	R	4.0	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01049		134		PLM43	R	0.04	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01056		25.5		PLM43	R	0.40	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01057		0.145		PLM40	R	0.03	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01060	<	0.050		PLM43	R	0.05	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01065		4.2		PLM10	R	0.20	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01075	<	0.020		PLM43	R	0.02	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01080		31.0		PLM40	R	0.8	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01085		0.15	n	PLM10	R	0.08	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01090		23.3		PLM10	R	2.0	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01106		300		PLM43	R	2.2	LT-MDL		USGSNWQL
USGS	353219077153801	2014-05-07	09:00			EDT	K	USGS-WRD	WG			01130		0.59		PLM40	R	0.22	LT-MDL		USGSNWQL